Coeur d' Alene Basin Water-Quality Monitoring

Conducted in cooperation with the U.S. Environmental Protection Agency

Methods

The USGS samples surface water based on BEMP and associated Quality Assurance Project Plan requirements which reference USGS standard water-quality data collection procedures.

Samples are collected using non-metallic samplers and cross-sectional, depth-integrated sampling procedures. Samples are composited and subsampled using a polyethylene churn splitting device. Samples for total analyses are withdrawn directly from the splitting device. Samples for dissolved (smaller than 0.45 micrometer diameter) analyses are filtered through a 0.45 micrometer pore size, disposable capsule filter. Metal and nutrient samples are preserved with nitric and sulfuric acid, respectively, to a pH of less than 2, chilled to 4 degrees Celsius, and sent to the USGS National Water Quality Laboratory in Denver Colorado

Suspended sediment is collected as a separate cross-sectional, depth-integrated sample or as a subsample from the splitting device. Suspended sediment samples are sent to the USGS Cascades Volcano Observatory Sediment Laboratory in Vancouver Washington

Metals and hardness analyses are performed by inductively-coupled plasma atomic emission spectrometry (ICP-AES) and inductively-coupled plasma mass spectrometry (ICP-MS). Nutrient analyses are performed using conventional USGS analytical procedures and standard EPA methods.

Suspended sediment samples are analyzed for total concentration and sand/silt particle size.